Question Details

A container has two chambers of volumes V1 = 2 litres and V2 = 3 litres separated by a partition made of a thermal insulator. The chambers contain n1 = 5 and n2 = 4 moles of ideal gas at pressures p1 = 1 atm and p2 = 2 atm , respectively. When the partition is removed, the mixture attains an equilibrium pressure of    

Options

A

1.8 atm

B

1.3 atm

C

1.6 atm

D

1.4 atm

Show Answer

Correct Answer :

Option C

1.6 atm

1.6 atm

Solution :

**Step 1 – List the given data**

Volumes: V₁ = 2 L, V₂ = 3 L

Moles: n₁ = 5 mol, n₂ = 4 mol

Initial pressures: p₁ = 1 atm, p₂ = 2 atm

The total volume after the partition is removed is

V=V1+V2 = 2 L + 3 L = 5 L

Total moles of gas

n=n1+n2 = 5 mol + 4 mol = 9 mol

**Step 2 – Use the ideal‑gas law for each chamber before mixing**

For an ideal gas, 

pV=nRT

so the temperature in each chamber is

T1=p1V1n1R

T2=p2V2n2R

**Step 3 – Apply energy conservation (adiabatic, insulated container)**

Because the container is thermally insulated, the total internal energy stays constant. For an ideal gas the internal energy depends only on temperature, so the final temperature (T_f) satisfies

n1T1+n2T2=nTf

Substituting the expressions for T₁ and T₂ and cancelling the universal gas constant R gives

Tf=p1V1+p2V2n×R

where n = n₁ + n₂ = 9 mol.

**Step 4 – Find the final equilibrium pressure**

Using the ideal‑gas law again for the whole container:

p_f=nRTfV

Insert the expression for T_f and simplify (the factors n R cancel):

p_f=p1V1+p2V2V1+V2

Plug in the numbers:

p_f=1×2+2×32+3

This evaluates to

p_f=85=1.6atm

**Conclusion** – The equilibrium pressure after the partition is removed is **1.6 atm**, which matches the given correct option.

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