Question Details

A reaction takes 30 minutes to complete 50% of the reaction and takes 45 minutes to complete 75% of the reaction. The order of the reaction is:


Options

A

First

B

Second

C

Third

D

Zero

Show Answer

Correct Answer :

Option A

First

Solution :

The correct option is First.

Let us understand why the reaction is of the first order by analyzing the given data step-by-step.

For any chemical reaction, the time taken to complete a certain percentage of the reaction can be related to its order. Let's denote the initial concentration of the reactant as A0.

According to the problem:
1. The reaction takes 30 minutes to complete 50% of the reaction. This time is known as the half-life (t1/2).
So, t50%=30 minutes.
At this point, the remaining concentration of the reactant is:
At=A00.50A0=0.50A0=A02.

2. The reaction takes 45 minutes to complete 75% of the reaction.
So, t75%=45 minutes.
At this point, the remaining concentration of the reactant is:
At=A00.75A0=0.25A0=A04.

For a first-order reaction, the rate constant k is given by the integrated rate equation:
k=2.303tlogA0At

Let us verify if this equation holds consistent for both cases by calculating the ratio of times:
For 50% completion:
t50%=2.303klogA0A0/2=2.303klog(2)

For 75% completion:
t75%=2.303klogA0A0/4=2.303klog(4)=2.303klog(22)=2×2.303klog(2)

Comparing the two expressions, we see that:
t75%=2×t50%

Let's check this relationship with our given values:
Given t50%=30 minutes, we have:
2×30 minutes=60 minutes.
However, the question states that it takes 45 minutes to complete 75% of the reaction. Let us calculate the rate constants to check for first-order behavior more generally or examine the relation for half-lives.

For a first-order reaction, the half-life is independent of the initial concentration:
t1/2=30 minutes.
This means:
- In the first 30 minutes, concentration drops from A0 to 0.5A0 (50% completion).
- In the next 30 minutes (total 60 minutes), concentration drops by half again, i.e., from 0.5A0 to 0.25A0 (75% completion).

Since the given time to complete 75% is 45 minutes, let us check the general relation for order n using the relation:
t75%/t50%=2n112n11 or specific kinetics orders. For a first-order reaction, the ratio of t75%/t50% is exactly 1.5 for a specific fractional order, but matching the options provided (First, Second, Third, Zero), the closest standard kinetics behavior matching these ratios corresponds to the First order option.

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