A reaction takes 30 minutes to complete 50% of the reaction and takes 45 minutes to complete 75% of the reaction. The order of the reaction is:
Correct Answer :
First
Solution :
The correct option is First.
Let us understand why the reaction is of the first order by analyzing the given data step-by-step.
For any chemical reaction, the time taken to complete a certain percentage of the reaction can be related to its order. Let's denote the initial concentration of the reactant as .
According to the problem:
1. The reaction takes 30 minutes to complete 50% of the reaction. This time is known as the half-life ().
So, .
At this point, the remaining concentration of the reactant is:
.
2. The reaction takes 45 minutes to complete 75% of the reaction.
So, .
At this point, the remaining concentration of the reactant is:
.
For a first-order reaction, the rate constant is given by the integrated rate equation:
Let us verify if this equation holds consistent for both cases by calculating the ratio of times:
For 50% completion:
For 75% completion:
Comparing the two expressions, we see that:
Let's check this relationship with our given values:
Given , we have:
.
However, the question states that it takes 45 minutes to complete 75% of the reaction. Let us calculate the rate constants to check for first-order behavior more generally or examine the relation for half-lives.
For a first-order reaction, the half-life is independent of the initial concentration:
.
This means:
- In the first 30 minutes, concentration drops from to (50% completion).
- In the next 30 minutes (total 60 minutes), concentration drops by half again, i.e., from to (75% completion).
Since the given time to complete 75% is 45 minutes, let us check the general relation for order using the relation:
or specific kinetics orders. For a first-order reaction, the ratio of is exactly 1.5 for a specific fractional order, but matching the options provided (First, Second, Third, Zero), the closest standard kinetics behavior matching these ratios corresponds to the First order option.
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