Question Details

Consider 1 kg of an ideal gas at 1 bar and 300 K contained in a rigid and perfectly insulated container. The specific heat of the gas at constant volume cv is equal to 750 J-kg-1K-1. A stirrer performs 225 kJ of work on the gas. Assume that the container does not participate in the thermodynamic interaction. The final pressure of the gas will be ______ bar (in integer).

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Correct Answer :

Correct answer is : 2

Solution :

The correct answer is 2.

As shown in the schematic diagram of the container, an ideal gas is kept inside a rigid, perfectly insulated vessel with a stirrer mechanism.

According to the First Law of Thermodynamics:
dQ=dU+dW
Here:
1. The container is perfectly insulated, meaning there is no heat transfer:
dQ=0
2. The container is rigid, which means there is no boundary or displacement work:
dWdisp=0
3. The only work done is the shaft work performed by the stirrer on the gas. Work done on the gas is negative:
dWstirrer=-225 kJ=-225000 J

Substituting these values into the first law equation:
0=dU+dWstirrer
dU=-dWstirrer=-(-225000 J)=225000 J

The change in internal energy for an ideal gas undergoing a constant volume process is related to the specific heat capacity at constant volume v by:
dU=mcv(T2-T1)

Given parameters from the problem description:
Mass of the gas, m=1 kg
Initial temperature, T1=300 K
Specific heat, cv=750 J kg-1 K-1

Substituting these values:
1×750×(T2-300)=225000
T2-300=225000750
T2-300=300
T2=600 K

Because the process takes place in a rigid container, the volume of the gas remains constant. For an ideal gas at constant volume, pressure is directly proportional to its absolute temperature:
P2P1=T2T1

Substituting the initial pressure P1=1 bar and the temperatures:
P2=1 bar×600300=2 bar

Therefore, the final pressure of the gas is 2 bar.

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