Question Details

Consider the following compounds :
KO2, H2O2 and H2SO4
The oxidation state of the underlined elements in them are, respectively,

Options

A

+2, –2, and +6

B

+1, –2, and +4

C

+4, –4, and +6

D

+1, –1, and +6

Show Answer

Correct Answer :

Option D

+1, –1, and +6

+1, -1, and +6

Solution :

We are asked to find the oxidation numbers of the underlined elements in the three compounds KO₂, H₂O₂ and H₂SO₄.

1. KO₂ – the underlined element is potassium (K).
In KO₂ the oxygen atoms form a superoxide ion O₂⁻. The total charge of the O₂ unit is –1, which means each oxygen atom has an oxidation state of –½. The overall charge of the neutral compound is 0, so the oxidation state of K must balance the –1 contributed by the O₂ unit:
xK+(-1)=0
Thus xK=+1. Therefore potassium is in the +1 oxidation state.

2. H₂O₂ – the underlined element is oxygen.
Hydrogen is always +1. Let the oxidation number of each oxygen be x.
2(+1)+2x=0
Solving gives 2+2x=0 ⇒ 2x=−2 ⇒ x=−1. Hence each oxygen in hydrogen peroxide is –1.

3. H₂SO₄ – the underlined element is sulfur.
Hydrogen is +1, oxygen is –2. Let the oxidation number of sulfur be y.
2(+1)+y+4(−2)=0
That is 2+y−8=0 ⇒ y=+6. So sulfur carries a +6 oxidation state.

Collecting the results, the oxidation states of the underlined elements are +1, -1, and +6, respectively.

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