Question Details

Direction for the question 41 to 45: Question is based on following passage:


Methyl nitrile  is hydrolysed to carboxylic acid in the presence of H+ or OH- as catalyst. An intermediate compound [A] is formed during this reaction.


The intermediate compound [Al is:

Options

A

Methyl isocyanide


B

Ethyl amine


C

Ethan amide


D

Methanamide


Show Answer

Correct Answer :

Option C

Ethan amide


Solution :

The correct option is Ethan amide.

Step-by-step Explanation:
1. Identification of the Starting Material:
The reaction scheme in the image starts with Methyl nitrile (also known as acetonitrile or ethanenitrile), which has the chemical formula:
CH3 - C N

2. Partial Hydrolysis (Formation of Intermediate [A]):
As shown in the reaction flowchart, treating methyl nitrile with water in the presence of an acid (H+) or base (OH-) catalyst results in partial hydrolysis. This converts the nitrile group (-CN) into an amide group (-CO-NH2). The intermediate compound [A] formed is ethanamide (commonly called acetamide):
CH3 - C N + H2 O CH3 - CO - NH2

3. Verification via Complete Hydrolysis to Carboxylic Acid [B]:
According to the scheme, heating (Δ) Intermediate [A] in acidic or basic conditions completes the hydrolysis to form Carboxylic Acid [B], which is ethanoic acid (acetic acid):
CH3 - CO - NH2 + H2 O H+/OH-,Δ CH3 - COOH + NH3

4. Verification via Hoffmann Bromamide Reaction (Formation of Amine [C]):
Intermediate [A] reacts with bromine and sodium hydroxide (Br2/NaOH). This is the Hoffmann bromamide degradation, which degrades an amide to a primary amine with one less carbon atom. Ethanamide degrades to methylamine, which corresponds to Amine [C]:
CH3 - CO - NH2 + Br2 + 4NaOH CH3 - NH2 + Na2 CO3 + 2NaBr + 2H2 O

5. Esterification (Formation of Sweet-Smelling Compound [D]):
Carboxylic Acid [B] (ethanoic acid) reacts with methanol (CH3OH) under acidic catalyst conditions (H+) to undergo esterification, producing the sweet-smelling ester methyl ethanoate (methyl acetate) as Compound [D]:
CH3 - COOH + CH3 OH H+ CH3 - COOCH3 + H2 O
All reactions in the scheme confirm that the intermediate compound [A] is ethanamide.

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