For a simple compressible system v, s, p and T are specific volume, specific entropy, pressure and temperature, respectively. As per Maxwell’s relations, (∂v /∂s)p is equal to
Correct Answer :
(∂T/∂p)s
(∂T/∂p)s
Solution :
To find the thermodynamic relation equal to , we can derive it from the fundamental thermodynamic relations and Maxwell's relations.
Let's start with the definition of enthalpy, :
where is internal energy, is pressure, and is specific volume.
The differential form of enthalpy is given by:
where is temperature and is specific entropy.
Since enthalpy is a state function, its differential is an exact differential of the form:
Comparing the coefficients of and in the two equations for , we get:
and
According to Euler's reciprocity relation for an exact differential of the form , the mixed second-order partial derivatives are equal:
Applying this mathematical theorem to , we obtain:
Therefore, as per Maxwell's relations, the term is equal to .
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