Question Details

For an ideal gas, starting from state point 1, two different processes take place. The corresponding final states in these two processes 2 and 3, lying on same isotherm. If P and h represent pressure and enthalpy, respectively, then which one of the following is correct?

Options

A

h2 > h

B

h2 = h3 

C

P2h3 = P3h2

D

P3h3 = P2h2

Show Answer

Correct Answer :

Option B

h2 = h3 

Solution :

The correct option is h2 = h3.

To understand why this is correct, we can analyze the thermodynamic properties of an ideal gas.
For an ideal gas, enthalpy (h) is a function of temperature (T) only. This relationship is defined by Joule's law of thermodynamics, which states:
h = f ( T ) Specifically, the change in enthalpy is given by:
d h = C p d T where Cp is the specific heat capacity at constant pressure, and dT is the change in temperature.

The problem states that the final states 2 and 3 lie on the same isotherm.
An isotherm is a line or curve of constant temperature. Therefore, the temperature at state 2 is equal to the temperature at state 3:
T 2 = T 3

Since the enthalpy of an ideal gas depends solely on its temperature, and states 2 and 3 are at the same temperature, their enthalpies must be equal:
h 2 = h 3 Thus, the relationship h2 = h3 holds true regardless of the paths taken to reach these states from state 1, or their final pressures.

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