Question Details

For diatomic gas, find the ratio Q : ∆U :W for isobaric process.

Options

A

2 : 5 : 7

B

2 : 3 : 5

C

2 : 7 : 3

D

7 : 5 : 2

Show Answer

Correct Answer :

Option D

7 : 5 : 2

Solution :

The correct option is 7 : 5 : 2.

Let us find the ratio of heat supplied (Q), change in internal energy (ΔU), and work done (W) for a diatomic gas undergoing an isobaric process (constant pressure).

For an isobaric process, the heat supplied to the gas is given by:
Q=nCpΔT
where n is the number of moles, Cp is the molar heat capacity at constant pressure, and ΔT is the change in temperature.

The change in internal energy is given by:
ΔU=nCvΔT
where Cv is the molar heat capacity at constant volume.

According to the first law of thermodynamics, the work done during the process is:
W=Q-ΔU=n(Cp-Cv)ΔT=nRΔT
where R is the universal gas constant.

For a diatomic gas, the degrees of freedom (f) at moderate temperatures is 5. Thus, the molar heat capacities are:
Cv=52R
and
Cp=Cv+R=72R

Substituting these values, we get:
Q=n72RΔT

ΔU=n52RΔT

W=nRΔT

Now, taking the ratio Q:ΔU:W:
Q:ΔU:W=72nRΔT:52nRΔT:nRΔT
Dividing each term by nRΔT gives:
Q:ΔU:W=72:52:1
Multiplying by 2 to clear the denominators yields the final ratio:
Q:ΔU:W=7:5:2

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