For He+, a transition takes place from the orbit of radius 105.8 pm to the orbit of radius 26.45 pm. The wavelength (in nm) of the emitted photon during the transition is:
[Use:
Bohr radius, a = 52.9 pm
Rydberg constant, RH = 2.2 × 10−18 J
Planck’s constant, h = 6.6 × 10−34 J s
Speed of light, c = 3 × 108 m s−1]
Correct Answer :
Solution :
The correct answer is 30.
Step 1: Understand the given data
For a helium ion (He+):
Atomic number, Z = 2
Initial orbit radius, rinitial = 105.8 pm
Final orbit radius, rfinal = 26.45 pm
Bohr radius for hydrogen atom, a0 = 52.9 pm
Rydberg constant in terms of energy, RH = 2.2 × 10−18 J
Planck's constant, h = 6.6 × 10−34 J s
Speed of light, c = 3 × 108 m s−1
Step 2: Find the principal quantum numbers (n1 and n2)
The radius of the n-th orbit for a hydrogen-like ion is given by the formula:
Rearranging for n2:
For the initial state (rinitial = 105.8 pm):
For the final state (rfinal = 26.45 pm):
Thus, the transition occurs from n2 = 2 to n1 = 1.
Step 3: Calculate the energy of the emitted photon
The energy difference (ΔE) between the two energy levels for a hydrogen-like system is:
Substituting n1 = 1, n2 = 2, Z = 2, and RH = 2.2 × 10−18 J:
Step 4: Calculate the wavelength (λ) of the emitted photon
Using the relation between photon energy and wavelength:
Substitute the given values:
Converting the wavelength to nanometers (nm):
Therefore, the wavelength of the emitted photon is 30 nm.
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