Question Details

If the rate constant of a reaction is 0.03 s-1 , how much time does it take for 7.2 mol L-1 concentration of the reactant to get reduced to 0.9 mol L-1?
(Given: log2 = 0.301 )

Options

A

21.0 s


B

69.3 s


C

23.1 s

D

210 s

Show Answer

Correct Answer :

Option B

69.3 s


69.3 s

Solution :

For a first‑order reaction the concentration changes with time according to

t=1kln(C_0C)

where

  • k is the rate constant (0.03 s⁻¹),
  • C_0 is the initial concentration (7.2 mol L⁻¹),
  • C is the final concentration (0.9 mol L⁻¹),
  • t is the time required.

First compute the concentration ratio:

C_0C=7.20.9=8

The natural logarithm can be evaluated using the given common‑log value log2=0.301. Because

log10(8)=log10(23)=3log10(2)

and the problem supplies log10(2)=0.301, we obtain

log10(8)=30.301=0.903

Convert the common log to a natural log using ln(x)=2.303log10(x):

ln(8)=2.3030.9032.08

Now substitute into the time equation:

t=10.032.0869.3 s

Therefore, it takes approximately **69.3 seconds** for the concentration to drop from 7.2 mol L⁻¹ to 0.9 mol L⁻¹.

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