Correct Answer :
69.3 s
Solution :
For a first‑order reaction the concentration changes with time according to
where
First compute the concentration ratio:
The natural logarithm can be evaluated using the given common‑log value . Because
and the problem supplies , we obtain
Convert the common log to a natural log using :
Now substitute into the time equation:
Therefore, it takes approximately **69.3 seconds** for the concentration to drop from 7.2 mol L⁻¹ to 0.9 mol L⁻¹.
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