Question Details

Increasing order of oxidation states of transition metal oxides will be:

[A] The oxidation state of titanium in titanium dioxide is commonly assumed to be +4.
[B] MnO 4 = x + 4 ( 2 ) = 1 x = 7
[C] VO 2 + = x + 2 ( 2 ) = 1 x = 5
[D] CrO 4 2 = x + 4 ( 2 ) = 2 x = 6
[E] The oxidation number of Ni in Ni (CO) 4 is +2.

Choose the correct answer from the options given below:

Options

A

(B) < (D) < (C) < (A) < (E)


B

(E) < (C) < (A) < (D) < (B)

C

(E)<(A) < (C) < (D) < (B)


D

(B) <(A) < (C) < (D) < (E)

Show Answer

Correct Answer :

Option C

(E)<(A) < (C) < (D) < (B)


Solution :

The correct option is (E) < (A) < (C) < (D) < (B).

To determine the correct increasing order of the oxidation states of the transition metal species, let us calculate or identify the oxidation state for each given transition metal one by one:

[A] Titanium in titanium dioxide (TiO2):
Oxygen generally has an oxidation state of -2. Let the oxidation state of titanium (Ti) be x. Since TiO2 is a neutral molecule:
x + 2 ( 2 ) = 0 x = + 4
Thus, the oxidation state of titanium in TiO2 is +4.

[B] Manganese in permanganate ion (MnO4-):
Let the oxidation state of manganese (Mn) be x. The overall charge of the ion is -1:
x + 4 ( 2 ) = 1 x 8 = 1 x = + 7
Thus, the oxidation state of manganese in MnO4- is +7.

[C] Vanadium in dioxovanadium(V) ion (VO2+):
Let the oxidation state of vanadium (V) be x. The overall charge of the ion is +1:
x + 2 ( 2 ) = + 1 x 4 = 1 x = + 5
Thus, the oxidation state of vanadium in VO2+ is +5.

[D] Chromium in chromate ion (CrO42-):
Let the oxidation state of chromium (Cr) be x. The overall charge of the ion is -2:
x + 4 ( 2 ) = 2 x 8 = 2 x = + 6
Thus, the oxidation state of chromium in CrO42- is +6.

[E] Nickel in nickel tetracarbonyl (Ni(CO)4):
Carbon monoxide (CO) is a neutral ligand with a charge of 0. Let the oxidation state of nickel (Ni) be x:
x + 4 ( 0 ) = 0 x = 0
Thus, the oxidation state of nickel in Ni(CO)4 is 0.

Comparing the calculated oxidation states:
• [E] Ni = 0
• [A] Ti = +4
• [C] V = +5
• [D] Cr = +6
• [B] Mn = +7

Arranging them in increasing order of oxidation states:
0 < +4 < +5 < +6 < +7
Which corresponds to:
(E) < (A) < (C) < (D) < (B)

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