Question Details

Rate of a reaction changes from  2.48 × 10 3  mol l 1 sec 1 to 4.96 × 10 3 mol l 1 sec 1  when concentration of reactant is changed from

 0.6 M to 2.4 M respectively, the order of reaction is:


Options

A

2

B

zero

C

0.5

D

3

Show Answer

Correct Answer :

Option C

0.5

Solution :

The correct option is 0.5.

Let's understand how the order of the reaction is determined step-by-step.

Step 1: Understand the Rate Law
The rate of a chemical reaction (R) depends on the concentration of the reactant ([A]) raised to the power of its order (n). This relationship is given by the rate law formula:
R=k[A]n
where:
- R is the rate of reaction,
- k is the rate constant,
- [A] is the concentration of the reactant, and
- n is the order of the reaction.

Step 2: Set up equations with the given data
From the question, we have two different sets of conditions:
1. Initial rate, R1=2.48×10-3 mol L-1 s-1 when the concentration [A]1=0.6 M.
This gives the equation:
2.48×10-3=k(0.6)n --- (Equation 1)

2. Final rate, R2=4.96×10-3 mol L-1 s-1 when the concentration [A]2=2.4 M.
This gives the equation:
4.96×10-3=k(2.4)n --- (Equation 2)

Step 3: Solve for the order of reaction (n)
Divide Equation 2 by Equation 1:
4.96×10-32.48×10-3=k(2.4)nk(0.6)n
Simplifying both sides:
2=(2.40.6)n
Since 2.40.6=4, we have:
2=4n
We can write 4 as 22:
21=(22)n
21=22n

By comparing the exponents:
1=2n
n=12=0.5

Therefore, the order of the reaction is 0.5.

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