Question Details

The density (in g cm-3 ) of the metal which forms a cubic close packed (ccp) lattice with an axial distance (edge length) equal to 400 pm is ______.


Use: Atomic mass of metal = 105.6 amu and Avogadro’s constant = 6 × 1023 mol–1

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Correct Answer :

11

Solution :

To find the density of the metal, we use the formula for the density (d) of a crystalline solid:
d=Z×Ma3×NA

Let us identify the given values:
1. Type of lattice: Cubic close packed (ccp), which is equivalent to a face-centered cubic (fcc) lattice. Therefore, the number of atoms per unit cell (Z) is 4.
2. Molar mass of the metal (M): The atomic mass is given as 105.6 amu, which corresponds to a molar mass of 105.6 g mol-1.
3. Edge length (a): 400 pm = 400 × 10-12 m = 400 × 10-10 cm = 4 × 10-8 cm.
4. Avogadro's constant (NA): 6 × 1023 mol-1.

Now, let us calculate the volume of the unit cell (a3):
a3=(4×10-8 cm)3=64×10-24 cm3

Substitute all the values into the density formula:
d=4×105.664×10-24×6×1023

Simplify the denominator:
64×10-24×6×1023=384×10-1=38.4

Now, calculate the final value of the density:
d=422.438.4=11 g cm-3

Thus, the density of the metal is 11.00 g cm-3.

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