2-Methylpropan-2-ol is commonly known as:
Correct Answer :
tert-butyl alcohol
Solution :
The correct answer is tert-butyl alcohol.
Let's break down the naming step-by-step to understand why 2-methylpropan-2-ol is commonly known as tert-butyl alcohol:
1. IUPAC Name Breakdown: 2-Methylpropan-2-ol
- The parent chain is "propan", which indicates a three-carbon chain:
- The suffix "-2-ol" indicates that a hydroxyl group () is attached to the second carbon ().
- The prefix "2-methyl" indicates that a methyl group () is also attached to the second carbon ().
- Combining these, the structural formula is:
2. Common Name Derivation: tert-Butyl Alcohol
- The molecule contains a total of four carbon atoms (three in the main propan chain and one in the methyl branch). A four-carbon alkyl group is called a butyl group.
- The carbon atom that is bonded to the hydroxyl group () is directly attached to three other carbon atoms (the two outer carbons of the propane chain and the carbon of the methyl group).
- A carbon atom bonded to three other carbons is classified as a tertiary (or tert-) carbon.
- Therefore, the alkyl radical is a tert-butyl group, and the alcohol is commonly named tert-butyl alcohol (or tertiary-butyl alcohol).
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