Question Details

2-Methylpropan-2-ol is commonly known as:

Options

A

tert-butyl alcohol

B

prim-propyl alcohol

C

ethyl alcohol

D

methanol

Show Answer

Correct Answer :

Option A

tert-butyl alcohol

Solution :

The correct answer is tert-butyl alcohol.

Let's break down the naming step-by-step to understand why 2-methylpropan-2-ol is commonly known as tert-butyl alcohol:

1. IUPAC Name Breakdown: 2-Methylpropan-2-ol
- The parent chain is "propan", which indicates a three-carbon chain:
C 1 - C 2 - C 3
- The suffix "-2-ol" indicates that a hydroxyl group (-OH) is attached to the second carbon (C2).
- The prefix "2-methyl" indicates that a methyl group (-CH3) is also attached to the second carbon (C2).
- Combining these, the structural formula is:
( C H 3 ) 3 C - O H

2. Common Name Derivation: tert-Butyl Alcohol
- The molecule contains a total of four carbon atoms (three in the main propan chain and one in the methyl branch). A four-carbon alkyl group is called a butyl group.
- The carbon atom that is bonded to the hydroxyl group (-OH) is directly attached to three other carbon atoms (the two outer carbons of the propane chain and the carbon of the methyl group).
- A carbon atom bonded to three other carbons is classified as a tertiary (or tert-) carbon.
- Therefore, the alkyl radical is a tert-butyl group, and the alcohol is commonly named tert-butyl alcohol (or tertiary-butyl alcohol).

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