Question Details

Calculate work in following process during A to B, in following graph. (Given (CV = 3R)

Options

A

–6.2 L.atm

B

–8.3 L.atm

C

–4.8 L.atm

D

–9.2 L.atm

Show Answer

Correct Answer :

Option B

–8.3 L.atm

Solution :

To find the work done during the process from state A to state B, we first analyze the parameters given in the P-V diagram:
At state A:
Pressure, PA=8 atm
Volume, VA=0.5 L

At state B:
Pressure, PB=1 atm
Volume, VB=4 L

Now, let us check the product of pressure and volume at both states A and B:
At state A: PAVA=8×0.5=4 L·atm
At state B: PBVB=1×4=4 L·atm

Since the product of pressure and volume remains constant (PV=constant), this indicates that the temperature of the system is constant throughout the process. Thus, the path from A to B represents a reversible isothermal expansion of an ideal gas.

According to the IUPAC convention in thermodynamics, the work done (W) during a reversible isothermal expansion is given by:
W=-nRTlnVBVA

Since nRT=PV=4 L·atm, we can substitute this value into the equation:
W=-(4 L·atm)×ln4 L0.5 L

Simplify the natural log term:
W=-4×ln(8) L·atm
Using the logarithmic property ln(xy)=yln(x):
W=-4×ln(23) L·atm
W=-4×3ln(2) L·atm
W=-12×ln(2) L·atm

Given that ln(2)0.693:
W-12×0.693 L·atm
W-8.316 L·atm

Rounding to one decimal place, we obtain:
W-8.3 L·atm

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