Question Details

Choose the correct answer from the options given below.

Options

A

(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)

B

(a)-(iii), (b)-(ii), (c)-(i), (d)-(iv)

C

(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)

D

(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)

Show Answer

Correct Answer :

Option D

(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)

(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)

Solution :

To find the correct match, let us analyze each reaction given in List - I and identify its name from List - II:

(a) Benzene reacting with CO and HCl in the presence of anhydrous AlCl3 and CuCl:
When benzene or its derivatives are treated with carbon monoxide and hydrogen chloride in the presence of anhydrous aluminium chloride (AlCl3) or cuprous chloride (CuCl), it yields benzaldehyde or substituted benzaldehyde. This reaction is known as the Gattermann-Koch reaction.
Therefore, (a) matches with (ii).

(b) R-CO-CH3 + NaOX → Products:
Methyl ketones containing the CH3-CO- group react with sodium hypohalite (NaOX) to produce a haloform (CHX3) and the sodium salt of the corresponding carboxylic acid. This reaction is known as the Haloform reaction.
Therefore, (b) matches with (iii).

(c) R-CH2-OH + R'-COOH in the presence of concentrated H2SO4:
When an alcohol reacts with a carboxylic acid in the presence of an acid catalyst like concentrated sulfuric acid (H2SO4), an ester and water are formed. This condensation reaction is known as Esterification.
Therefore, (c) matches with (iv).

(d) R-CH2-COOH reacting with (i) X2/Red P and (ii) H2O:
Carboxylic acids containing an α-hydrogen are halogenated at the α-position upon treatment with halogen (Cl2 or Br2) in the presence of a small amount of red phosphorus, followed by hydrolysis. This reaction is known as the Hell-Volhard-Zelinsky (HVZ) reaction.
Therefore, (d) matches with (i).

Combining all the matches:
• (a) → (ii)
• (b) → (iii)
• (c) → (iv)
• (d) → (i)

Thus, the correct option is (a)-(ii), (b)-(iii), (c)-(iv), (d)-(i).

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