Question Details

Consider the following compounds:


KO2, H2O2 and H2SO4


The oxidation states of the underlined elements in them are, respectively,

Options

A

+1, −1, and +6

B

+2, −2, and +6

C

+1, −2, and +4

D

+4, −4, and +6

Show Answer

Correct Answer :

Option A

+1, −1, and +6

+1, −1, and +6

Solution :

The correct option is: +1, −1, and +6

Let us find the oxidation states of the underlined elements in each of the given compounds step-by-step:

1. Oxidation state of K in KO2 (Potassium superoxide):
Potassium (K) is an alkali metal (Group 1 element). In all its stable compounds, alkali metals always exhibit an oxidation state of +1.
In KO2, which is potassium superoxide, the superoxide ion is O2-, where the two oxygen atoms share a overall charge of -1 (giving an average oxidation state of -0.5 for each oxygen).
Thus, the oxidation state of K in KO2 is +1.

2. Oxidation state of O in H2O2 (Hydrogen peroxide):
Hydrogen peroxide is a peroxide compound. Hydrogen (H) has an oxidation state of +1 when bonded to non-metals.
Let the oxidation state of O be x.
Since the overall molecule is neutral, the sum of the oxidation states of all atoms must be zero:
2(+1)+2(x)=0
2+2x=0
2x=-2
x=-1
Therefore, the oxidation state of O in H2O2 is −1.

3. Oxidation state of S in H2SO4 (Sulfuric acid):
In sulfuric acid, hydrogen (H) has an oxidation state of +1 and oxygen (O) has an oxidation state of -2.
Let the oxidation state of S be y.
Since the molecule is neutral, the sum of the oxidation states of all atoms is zero:
2(+1)+y+4(-2)=0
2+y-8=0
y-6=0
y=+6
Therefore, the oxidation state of S in H2SO4 is +6.

Comparing these values with the options, we get:
Oxidation state of K = +1
Oxidation state of O = −1
Oxidation state of S = +6
Hence, the oxidation states are, respectively, +1, −1, and +6.

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