Question Details

Find incorrect statement among the following

Options

A

C13 is a radioactive isotope

B

Covalency of carbon greater than 4 is possible

C

Carbon can exhibit +2 & +4 oxidation state

D

In group-14, CO2 is most acidic

Show Answer

Correct Answer :

Option B

Covalency of carbon greater than 4 is possible

Covalency of carbon greater than 4 is possible

Solution :

The correct option (incorrect statement) is: Covalency of carbon greater than 4 is possible

Let us analyze the statement step-by-step to understand why it is incorrect:

1. Electronic Configuration of Carbon:
Carbon has an atomic number of 6. Its ground-state electronic configuration is:
1s22s22p2

2. Absence of d-Orbitals:
Carbon belongs to the second period of the periodic table, which means its valence shell is the second shell (n=2). The second shell contains only s and p subshells (specifically, one 2s orbital and three 2p orbitals). It lacks vacant d-orbitals because d-orbitals only exist for shells with n3.

3. Limit on Bond Formation:
Because carbon has only 4 valence orbitals available for bonding, it can share a maximum of 4 pairs of electrons. Without available d-orbitals, it cannot expand its valence shell to accommodate more than 8 electrons (octet rule). Therefore, the maximum covalency carbon can exhibit is 4.

4. Conclusion:
Since a covalency greater than 4 is impossible for carbon, the statement "Covalency of carbon greater than 4 is possible" is false, making it the incorrect statement.

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