Question Details

Given below are certain cations. Using inorganic qualitative analysis, arrange them in increasing group number from 0 to VI.

A.   Al3+               B.   Cu2+

C.   Ba2+              D.   Co2+

E.   Mg2+

Choose the correct answer from the options given below.

Options

A

B, A, D, C, E

B

B, C, A, D, E

C

E, C, D, B, A

D

E, A, B, C, D

Show Answer

Correct Answer :

Option A

B, A, D, C, E

B, A, D, C, E

Solution :

To arrange the given cations in increasing order of their group numbers in inorganic qualitative analysis, we first identify the analytical group for each cation:

1. Cu2+ (Copper ion): Belongs to Group II. The group reagent is H2S gas in the presence of dilute HCl.
2. Al3+ (Aluminium ion): Belongs to Group III. The group reagent is NH4OH in the presence of NH4Cl.
3. Co2+ (Cobalt ion): Belongs to Group IV. The group reagent is H2S gas in the presence of NH4OH and NH4Cl.
4. Ba2+ (Barium ion): Belongs to Group V. The group reagent is (NH4)2CO3 in the presence of NH4OH and NH4Cl.
5. Mg2+ (Magnesium ion): Belongs to Group VI. The group reagent is (NH4)2HPO4 in the presence of NH4OH.

Now, we list the cations alongside their respective group numbers:
- B. Cu2+: Group II
- A. Al3+: Group III
- D. Co2+: Group IV
- C. Ba2+: Group V
- E. Mg2+: Group VI

Arranging these in increasing order of group numbers (from II to VI) gives us:
B (Group II) < A (Group III) < D (Group IV) < C (Group V) < E (Group VI)

Therefore, the correct sequence is B, A, D, C, E.

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