Identify 'A' in the following reaction :
Correct Answer :
Solution :
The correct product 'A' is butane, represented by the structural formula:
CH3-CH2-CH2-CH3
Reaction Analysis:
1. Reactant: The starting material shown in the question is butanone (also known as ethyl methyl ketone), which has the structure:
CH3-CO-CH2-CH3
2. Reagents: The reaction is conducted in two steps:
(i) Hydrazine ()
(ii) Potassium hydroxide (KOH) in the presence of ethylene glycol as a high-boiling solvent under heating conditions.
3. Reaction Name: This specific set of reagents is used to perform the Wolff-Kishner reduction.
4. Mechanism and Transformation:
During the Wolff-Kishner reduction, the carbonyl group () of aldehydes or ketones is selectively reduced to a methylene group (). The reaction proceeds via the formation of a hydrazone intermediate (), which then undergoes base-promoted decomposition with the elimination of nitrogen gas ():
Thus, the carbonyl carbon of butanone is reduced to form the corresponding alkane, which is butane.
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