Question Details

Identify the correct order of organic compounds in the following chemical reaction:



(A) CH3MgBr
(B) CH3Br
(C) CH3Cl
(D) CH4


Choose the correct answer from the options given below:

Options

A

(B), (A), (D), (C)

B

(A), (C), (B), (D)

C

(B), (A), (C), (D)

D

(C), (B), (D), (A)

Show Answer

Correct Answer :

Option C

(B), (A), (C), (D)

Solution :

The correct option is (B), (A), (C), (D).

By analyzing the chemical reaction scheme shown in the image:
?+MgDry Ether?H2O?Cl2,Δ?

We can identify each of the organic compounds in the sequence step-by-step:

Step 1: Preparation of Grignard Reagent
Alkyl halides react with magnesium metal (Mg) in the presence of dry ether to yield organomagnesium halides, commonly known as Grignard reagents. In this reaction, methyl bromide, CH3Br (B), reacts with magnesium to form methylmagnesium bromide, CH3MgBr (A):
CH3Br+MgDry EtherCH3MgBr
Therefore, the first reactant is (B) and the second product is (A).

Step 2: Hydrolysis of the Grignard Reagent
Grignard reagents are highly reactive bases and react instantly with proton donors such as water (H2O). The methyl group in methylmagnesium bromide (A) takes a proton from water to produce methane, CH4 (D):
CH3MgBr+H2OCH4+Mg(OH)Br
Thus, the third compound in the sequence is (D).

Step 3: Chlorination of Alkane
Methane (D) undergoes free-radical halogenation when treated with chlorine gas (Cl2) and heat (Δ) to form methyl chloride, CH3Cl (C):
CH4+Cl2ΔCH3Cl+HCl
Thus, the final product is (C).

Tracing the reaction sequence gives the order: (B) → (A) → (D) → (C). According to the provided options, this matches the correct option (B), (A), (C), (D).

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