Question Details

Identify the incorrect statement from the following:

Options

A

Carbon has the ability to form pπ− pπ multiple bond with itself.

B

ECl3, where E = B and Al, is a monomer when E = B and a dimer when E =Al.

C

Oxygen exhibits only −2 oxidation state.

D

The order of catenation property of Group 14 elements is C ≫ Si > Ge =Sn.

Show Answer

Correct Answer :

Option C

Oxygen exhibits only −2 oxidation state.

Oxygen exhibits only −2 oxidation state.

Solution :

The statement “Oxygen exhibits only −2 oxidation state.” is incorrect because oxygen can show several oxidation numbers besides −2.


1. O0 in its elemental form (O2). In diatomic oxygen each atom shares electrons equally, resulting in an oxidation state of 0.


2. O−1 in peroxides such as hydrogen peroxide (H2O2) and barium peroxide (BaO2). Here each oxygen atom is bonded to another oxygen atom, giving an overall −2 charge split equally, i.e., each oxygen is −1.


3. O−½ in superoxides like potassium superoxide (KO2). The O2 unit carries a −1 charge, so each oxygen has an average oxidation state of −½.


4. Positive oxidation states are also possible when oxygen is bonded to more electronegative elements:

  • O+1 in dioxygen difluoride (O2F2) where each oxygen is bonded to two fluorine atoms.
  • O+2 in oxygen difluoride (OF2) where oxygen is less electronegative than fluorine.

Therefore, oxygen does not exhibit only the −2 oxidation state; it can have 0, −1, −½, +1, and +2 oxidation numbers depending on the chemical environment. This makes the given statement false.

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