Identify the incorrect statement from the following:
Correct Answer :
Oxygen exhibits only −2 oxidation state.
Solution :
The statement “Oxygen exhibits only −2 oxidation state.” is incorrect because oxygen can show several oxidation numbers besides −2.
1. in its elemental form (O2). In diatomic oxygen each atom shares electrons equally, resulting in an oxidation state of 0.
2. in peroxides such as hydrogen peroxide (H2O2) and barium peroxide (BaO2). Here each oxygen atom is bonded to another oxygen atom, giving an overall −2 charge split equally, i.e., each oxygen is −1.
3. in superoxides like potassium superoxide (KO2). The O2 unit carries a −1 charge, so each oxygen has an average oxidation state of −½.
4. Positive oxidation states are also possible when oxygen is bonded to more electronegative elements:
Therefore, oxygen does not exhibit only the −2 oxidation state; it can have 0, −1, −½, +1, and +2 oxidation numbers depending on the chemical environment. This makes the given statement false.
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