Question Details

Match List I with List II

List-I
(Reaction)

List-II
(Reagents/Condition)

(A)
(I)
(B)
(II) C r O 3
(C)
(III) K M n O 4 / K O H , Δ
(D)
(IV) (i)  O 3 (ii)  Z n H 2 O

Choose the correct answer from the options given below:

Options

A

A-IV, B-I, C-III, D-II

B

A-III, B-I, C-II, D-IV

C

A-IV, B-I, C-II, D-III

D

A-I, B-IV, C-II, D-III

Show Answer

Correct Answer :

Option C

A-IV, B-I, C-II, D-III

A-IV, B-I, C-II, D-III

Solution :

The correct option is A-IV, B-I, C-II, D-III.

Let's analyze the reactions in List-I and match them with the reagents/conditions in List-II step-by-step:

1. Reaction (A):
The reactant shown in the image is bicyclohexylidene (two cyclohexyl rings connected by a double bond), which is cleaved and converted into two molecules of cyclohexanone:
C12H202C6H10O
This is an oxidative cleavage of an alkene across its double bond to form carbonyl compounds. The appropriate reagent for this conversion is reductive ozonolysis, which corresponds to (IV):
(i) O3 (ii) Zn - H2O
Thus, A matches with IV.

2. Reaction (B):
The reactant shown in the image is benzene, which is converted to benzophenone:
C6H6C6H5COC6H5
This is a Friedel-Crafts acylation reaction. Benzene reacts with benzoyl chloride in the presence of a Lewis acid catalyst (anhydrous aluminium chloride) to form benzophenone. The reagent shown in the image for (I) is benzoyl chloride and anhydrous aluminium chloride:
C6H5COCl / Anhydrous AlCl3
Thus, B matches with I.

3. Reaction (C):
The reactant shown in the image is cyclohexanol, which is oxidized to cyclohexanone (a ketone):
C6H11OHC6H10O
This represents the oxidation of a secondary alcohol to a ketone. The reagent used for this oxidation is chromium trioxide, which corresponds to (II):
CrO3
Thus, C matches with II.

4. Reaction (D):
The reactant shown in the image is ethylbenzene, which is converted to potassium benzoate:
C6H5CH2CH3C6H5COOK
This is the oxidation of the alkyl side chain of an aromatic ring to a carboxylic acid salt. The reagent used for this strong oxidation is alkaline potassium permanganate with heating, which corresponds to (III):
KMnO4 / KOH, Δ
Thus, D matches with III.

Combining all the correct matches, we obtain:
A-IV, B-I, C-II, D-III

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