One of the commonly used electrode is calomel electrode. Under which of the following categories calomel electrode comes ?
Correct Answer :
Metal – Insoluble Salt – Anion electrodes
Solution :
The correct answer is Metal – Insoluble Salt – Anion electrodes.
Let's understand the construction and classification of the calomel electrode step-by-step:
1. Definition and Construction:
A calomel electrode is a reference electrode that consists of mercury (a metal), a paste of mercurous chloride (, which is a sparingly soluble/insoluble salt), and a solution of potassium chloride (KCl, which provides the chloride anion, ).
2. Electrode Representation:
The electrode is represented as:
This representation clearly shows that it consists of a metal (Hg) in contact with its insoluble salt () and a common anion ().
3. Classification:
Because the potential of this electrode is determined by the concentration (or activity) of the anion () in equilibrium with the insoluble salt, it falls under the category of Metal – Insoluble Salt – Anion electrodes.
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