Question Details

One of the commonly used electrode is calomel electrode. Under which of the following categories calomel electrode comes ?

Options

A

Oxidation – Reduction electrodes

B

Metal – Insoluble Salt – Anion electrodes

C

Gas – Ion electrodes

D

Metal ion – Metal electrodes

Show Answer

Correct Answer :

Option B

Metal – Insoluble Salt – Anion electrodes

Metal – Insoluble Salt – Anion electrodes

Solution :

The correct answer is Metal – Insoluble Salt – Anion electrodes.

Let's understand the construction and classification of the calomel electrode step-by-step:
1. Definition and Construction:
A calomel electrode is a reference electrode that consists of mercury (a metal), a paste of mercurous chloride (Hg2Cl2, which is a sparingly soluble/insoluble salt), and a solution of potassium chloride (KCl, which provides the chloride anion, Cl-).
2. Electrode Representation:
The electrode is represented as:
Pt|Hg(l)|Hg2Cl2(s)|Cl-(aq)
This representation clearly shows that it consists of a metal (Hg) in contact with its insoluble salt (Hg2Cl2) and a common anion (Cl-).
3. Classification:
Because the potential of this electrode is determined by the concentration (or activity) of the anion (Cl-) in equilibrium with the insoluble salt, it falls under the category of Metal – Insoluble Salt – Anion electrodes.

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