Question Details

Read the following passage and answer the next five questions based on it.(32-36)


Battery or cell converts chemical energy of the redox reaction to electrical energy. In fuel cells (a galvanic cell), the chemical energy of combustion of fuels like H2, ethanol, etc., is directly converted to electrical energy. In a fuel cell, H2 and O2 react to produce electricity, where H2
gas is oxidized at the anode and oxygen is reduced at the cathode, and the reactions involved are:


Anode reaction:H2 + 2OH → 2H2O+2e
Cathode reaction:O2 + 2H2O +4e → 4OH


67.2 L of H2 at STP reacts in 15 minutes.


The number of moles of electrons produced in the oxidation of 67.2 L of H2 at STP is

Options

A

2 moles

B

4 moles

C

1 mole

D

6 moles

Show Answer

Correct Answer :

Option D

6 moles

Solution :

The correct option is 6 moles.

Step-by-step Explanation:

Step 1: Calculate the number of moles of hydrogen gas (H2) reacting at STP
At Standard Temperature and Pressure (STP), 1 mole of any ideal gas occupies a volume of 22.4 liters.
Given volume of H2 gas = 67.2 L
We can find the number of moles using the formula:
Number of moles of H 2 = Volume of gas at STP Molar volume at STP
Substituting the given values:
Number of moles of H 2 = 67.2 L 22.4 L/mol = 3 moles

Step 2: Determine the moles of electrons produced from the oxidation reaction
The oxidation half-reaction occurring at the anode of the fuel cell is:
H2 + 2OH- → 2H2O + 2e-
From this balanced chemical equation, we can see that:
1 mole of H2 gas produces 2 moles of electrons (e-) upon oxidation.

Step 3: Calculate the total moles of electrons produced by 3 moles of H2
Since 1 mole of H2 produces 2 moles of electrons:
Total moles of electrons = 3 moles of H 2 × 2 moles of e - /mole of H 2 = 6 moles
Therefore, the oxidation of 67.2 L of H2 at STP produces 6 moles of electrons.

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