Question Details

The calculated spin-only magnetic moment of Ti2+,3d2, is:

Options

A

2.84 BM

B

5.92 BM

C

4.90 BM

D

3.87 BM

Show Answer

Correct Answer :

Option A

2.84 BM

2.84 BM

Solution :

We need the spin‑only magnetic moment (μ) for the ion Ti2+ which has a 3d2 configuration.

1. Determine the number of unpaired electrons (n).
• A neutral Ti atom has the electron configuration [Ar] 3d2 4s2.
• Removing two electrons to form Ti2+ takes away the two 4s electrons, leaving only the two 3d electrons.
• In a free ion (or in a weak crystal field) the two 3d electrons occupy separate orbitals, so both are unpaired.
• Therefore, n = 2.

2. Use the spin‑only formula.
The spin‑only magnetic moment is given by

μ = sqrt(n · (n + 2))

where μ is expressed in Bohr magnetons (BM). This formula comes from μ = √[S(S+1)] · 2 · √3 · μB, which simplifies to the expression above when expressed in BM.

3. Insert n = 2 into the formula.
μ = sqrt(2 · (2 + 2)) = sqrt(2 · 4) = sqrt(8)

4. Evaluate the square root.
sqrt(8) ≈ 2.8284 BM.

5. Round to the usual reporting precision.
Rounding to two decimal places gives μ ≈ 2.84 BM.

Thus, the calculated spin‑only magnetic moment of Ti2+ (3d2) is 2.84 BM, which matches the provided correct option.

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