Question Details

The intermediate compound ‘X’ in the following chemical reaction is :

Options

A

B

C

D

Show Answer

Correct Answer :

Option C

Solution :

The correct answer is:


Explanation:

The given reaction represents the Etard reaction, which involves the partial oxidation of toluene (methylbenzene) to benzaldehyde using chromyl chloride (CrO2Cl2) in a non-polar solvent such as carbon disulfide (CS2) or carbon tetrachloride (CCl4).


Reaction Mechanism & Steps:

1. Formation of Chromium Complex (Intermediate 'X'):
When toluene reacts with chromyl chloride (CrO2Cl2) in carbon disulfide (CS2), chromyl chloride oxidizes the methyl group to form a brown-colored chromium complex intermediate 'X'.


The structure of this intermediate chromium complex is represented as:

C6H5CH(OCrOHCl)22

which corresponds to:


2. Acid Hydrolysis:
Subsequent acidic hydrolysis (H3O+) of this intermediate complex yields benzaldehyde (C6H5CHO).


Therefore, the intermediate compound 'X' is .

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  • JEE
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  • JEE
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