The linear structure is assumed by;
Correct Answer :
Both (2) and (3)
Solution :
The question asks which species are assumed to have a linear structure.
Option (1) SnCl2 is not linear. In the gas phase the tin atom uses an sp2 hybridisation, giving a trigonal‑pyramidal (or V‑shaped) geometry with a lone pair on tin.
Option (2) NCO‑ (the cyanate ion) contains a carbon atom bonded to nitrogen and oxygen. The central carbon is sp‑hybridised, forming a triple‑bond‑like arrangement N≡C–O⁻. The two regions of electron density lie opposite each other, resulting in a linear N–C–O arrangement.
Option (3) CS2 (carbon disulphide) also has a central carbon atom that is sp‑hybridised. It forms two double bonds C=S that are arranged 180° apart, giving a linear S–C–S geometry.
Since both NCO‑ (2) and CS2 (3) are linear, the correct choice is “Both (2) and (3)”.
Therefore, the linear structure is assumed by the species listed in options (2) and (3).
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