The monomer (X) involved in the synthesis of Nylon 6,6 gives positive carbylamine test. If 10 moles of X are analyzed using Dumas method, the amount (in grams) of nitrogen gas evolved is ______.
Use: Atomic mass of N (in amu) = 14
Correct Answer :
Solution :
Nylon 6,6 is a copolymer synthesized from two monomers: adipic acid (a dicarboxylic acid) and hexamethylenediamine (a diamine).
The carbylamine test is a characteristic chemical test for primary amines, where primary amines react with chloroform and ethanolic potassium hydroxide to produce foul-smelling carbylamines (isocyanides).
Between the two monomers, hexamethylenediamine (H2N-(CH2)6-NH2) contains primary amine groups and therefore gives a positive carbylamine test. Thus, monomer X is hexamethylenediamine.
From the molecular formula of hexamethylenediamine, we observe that each molecule contains 2 nitrogen (N) atoms. Therefore, 1 mole of monomer X contains 2 moles of nitrogen atoms.
In the Dumas method for the estimation of nitrogen, the organic nitrogen present in the compound is quantitatively converted to nitrogen gas (N2).
Since 1 mole of X contains 2 moles of N atoms, it will evolve exactly 1 mole of N2 gas:
Therefore, for 10 moles of monomer X, the number of moles of N2 gas evolved is:
We are given that the atomic mass of nitrogen (N) is 14. The molar mass of diatomic nitrogen gas (N2) is:
Now, we calculate the amount (in grams) of nitrogen gas evolved:
Thus, the amount of nitrogen gas evolved is 280 grams.
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