Question Details

The monomer (X) involved in the synthesis of Nylon 6,6 gives positive carbylamine test. If 10 moles of X are analyzed using Dumas method, the amount (in grams) of nitrogen gas evolved is ______.

Use: Atomic mass of N (in amu) = 14

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Correct Answer :

280

Solution :

Nylon 6,6 is a copolymer synthesized from two monomers: adipic acid (a dicarboxylic acid) and hexamethylenediamine (a diamine).

The carbylamine test is a characteristic chemical test for primary amines, where primary amines react with chloroform and ethanolic potassium hydroxide to produce foul-smelling carbylamines (isocyanides).

Between the two monomers, hexamethylenediamine (H2N-(CH2)6-NH2) contains primary amine groups and therefore gives a positive carbylamine test. Thus, monomer X is hexamethylenediamine.

From the molecular formula of hexamethylenediamine, we observe that each molecule contains 2 nitrogen (N) atoms. Therefore, 1 mole of monomer X contains 2 moles of nitrogen atoms.

In the Dumas method for the estimation of nitrogen, the organic nitrogen present in the compound is quantitatively converted to nitrogen gas (N2).

Since 1 mole of X contains 2 moles of N atoms, it will evolve exactly 1 mole of N2 gas:

1 mole of X 1 mole of N 2

Therefore, for 10 moles of monomer X, the number of moles of N2 gas evolved is:

Moles of N 2 = 10 moles

We are given that the atomic mass of nitrogen (N) is 14. The molar mass of diatomic nitrogen gas (N2) is:

Molar mass of N 2 = 2 × 14 g/mol = 28 g/mol

Now, we calculate the amount (in grams) of nitrogen gas evolved:

Mass of N 2 = Number of moles × Molar mass

Mass of N 2 = 10 moles × 28 g/mol = 280 grams

Thus, the amount of nitrogen gas evolved is 280 grams.

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