Question Details

The state of hybridization of C2, C3, C5 and C6 of the

.

Options

A

sp, sp2, sp3 and sp2

B

sp, sp3, sp2 and sp3

C

sp3, sp2, sp2 and sp

D

sp, sp2, sp2 and sp3

Show Answer

Correct Answer :

Option B

sp, sp3, sp2 and sp3

sp, sp3, sp2 and sp3

Solution :

The molecule shown in the image contains four carbon atoms of interest: C2, C3, C5 and C6. Their hybridization can be deduced by looking at the type and number of bonds each carbon forms.

C2: In the diagram C2 is attached to a triple bond (‒≡‒) with the neighboring carbon. A carbon involved in a triple bond uses one σ‑bond and two π‑bonds, requiring two hybrid orbitals for σ‑bonding and one unhybridized p‑orbital for each π‑bond. This corresponds to sp hybridization.

C3: C3 is shown forming four single σ‑bonds (to three other atoms and to a hydrogen). Four σ‑bonds arise from four equivalent sp3 hybrid orbitals, so C3 is sp3 hybridized.

C5: C5 participates in a double bond (‒=‒). A double bond consists of one σ‑bond and one π‑bond, which is produced by mixing one s orbital with two p orbitals, giving three hybrid orbitals. Hence C5 is sp2 hybridized.

C6: C6 forms only single σ‑bonds (to two carbons and two hydrogens). As with C3, four σ‑bonds mean the carbon uses four sp3 hybrid orbitals. Therefore C6 is sp3 hybridized.

Summarizing the hybridizations in the order presented (C2, C3, C5, C6) gives:

sp, sp3, sp2 \; and \; sp3.

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