What is the IUPAC name of the organic compound formed in the following chemical reaction ?
Correct Answer :
2-methyl butan-2-ol
Solution :
The correct answer is 2-methyl butan-2-ol.
Step-by-Step Explanation:
1. Identify the Reactants:
- Acetone (Propan-2-one): A ketone with the chemical structure containing a highly polar carbonyl group (C=O).
- Ethylmagnesium bromide (): A Grignard reagent that serves as a source of the nucleophilic ethyl group ().
2. Step 1: Nucleophilic Addition of Grignard Reagent:
The nucleophilic ethyl group () attacks the electrophilic carbonyl carbon of acetone in dry ether. The electron pair from the C=O double bond shifts to the oxygen atom, forming a magnesium salt intermediate:
3. Step 2: Acid Hydrolysis:
Subsequent protonation/hydrolysis of the alkoxide intermediate with water in an acidic medium () yields a tertiary alcohol:
4. IUPAC Nomenclature of the Product:
- The structure of the resulting alcohol is:
- The longest continuous carbon chain containing the hydroxyl (-OH) group has 4 carbon atoms, which corresponds to butane.
- Numbering the chain from the right side gives the lowest locants to the substituents:
• C1: (terminal right)
• C2: Carbon bonded to both the group and a methyl () substituent
• C3:
• C4: (terminal left)
- Combining these substituent locations, we have a methyl group at carbon-2 and the alcohol group at carbon-2.
- Therefore, the IUPAC name is 2-methyl butan-2-ol.
Access expert-curated educational resources and study materials—completely free.
Create, conduct, and manage professional online assessments with Mindyard. Perfect for teachers and institutes.
Copyright © 2026 Mindyard. All Rights Reserved.